Patent application number | Description | Published |
20100298499 | NOVEL LIVING RADICAL POLYMERIZATION METHOD USING A PHOSPHORUS COMPOUND OR NITROGEN COMPOUND AS A CATALYST - A highly active and environment-friendly catalyst for use in a living radical polymerization is provided. A catalyst for use in a living radical polymerization method is provided. The catalyst comprises a central element, which is selected from nitrogen and phosphorus, and at least one halogen atom, which is bound to the central element. A monomer having a radical reactive unsaturated bond is subjected to a radical polymerization reaction in the presence of the catalyst, thereby it is possible to obtain a polymer having narrow molecular weight distribution. The present invention has the merits such as low toxicity of the catalyst, a small amount of the catalyst being required, high solubility of the catalyst in the polymerization media, mild reaction conditions, no coloration, no odor (unnecessary post-treatment of molded products). The method of the present invention is more environment-friendly and economical than other living radical polymerization methods. | 11-25-2010 |
20110124832 | NOVEL LIVING RADICAL POLYMERIZATION METHOD USING ALCOHOL AS CATALYST - Provided is a low-cost, environmentally friendly living radical polymerization catalyst having high activity. The catalyst is used for a living radical polymerization method, and contains a central element consisting of oxygen and at least one halogen atom bound to the central element. Furthermore, an alcohol compound can be used as a catalyst precursor. By polymerizing a monomer in the presence of the catalyst, a polymer having narrow molecular weight distribution can be obtained, and the cost of the living radical polymerization can be remarkably reduced. The present invention is significantly more environmentally friendly and economically excellent than conventional living radical polymerization methods, due to advantages of the catalyst such as low toxicity of the catalyst, low amount of the catalyst necessary, high solubility of the catalyst, mild reaction conditions, and no coloration/no odor (which do not require a post-treatment for a molded article), and the like. | 05-26-2011 |
Patent application number | Description | Published |
20110112242 | METHOD FOR PRODUCING DYE POLYMER, DYE POLYMER AND USE OF THE SAME - Disclosed are a production process of a dye polymer having a dye content of from 1 to 50 wt %, and the dye polymer and its use. The production process includes subjecting an addition-polymerizable monomer to living radical polymerization by using, as a polymerization initiator, a dye having a polymerization initiating group enabling the living radical polymerization. The dye polymer and a composition of the dye polymer and a pigment are useful as good coloring agents for various products or articles. The colored products or articles are high in transparency, and are provided with high added value. The dye polymer can also be used as a dispersant for pigments, thereby making it possible to afford pigment dispersions excellent in dispersion properties and dispersion stability. | 05-12-2011 |
20120136131 | POLYMERIZATION INITIATOR FOR LIVING RADICAL POLYMERIZATION - Provided is a method of living radical polymerization which does not necessitate complicated and intricate synthesis of a dormant species and which is highly efficient. A halogenated derivative compound is used as a dormant species for initiating living radical polymerization. The derivative compound is obtained by halogenating an alcohol compound having a non-conjugated structure or an amine compound having a non-conjugated structure with a halogenating agent capable of halogenating an alcohol or amine. A radical produced by elimination of halogen from the halogenated derivative compound is allowed to react with the unsaturated bond of the monomer. Thus, the monomer, which has a radical-reactive unsaturated bond, is polymerized by living radical polymerization. Preferably, the halogenating agent is a compound (NIS or the like) which also has a function as a catalyst. | 05-31-2012 |
20130196064 | PROCESS FOR PRODUCING BLOCK POLYMER, COATED PIGMENT AND AQUEOUS PIGMENT DISPERSION - Disclosed are an aqueous pigment dispersion containing at least a pigment, water, a high-molecular dispersant, and an alkali. The high-molecular dispersant is a diblock polymer having a formula (1) of A-B or a triblock polymer having a formula (2) of A-B-C. The diblock or triblock polymer is a diblock or triblock polymer obtained by polymerizing addition-polymerizable monomers with a radical generator while using an organic iodide as a polymerization initiating compound and an organic phosphorus compound, organic nitrogen compound or organic oxygen compound as a catalyst. Also disclosed are a production method and use of the aqueous pigment dispersion. With the high-molecular dispersant obtained by a simple living radical polymerization process free of the problems of conventional living radical polymerization and having a precisely-controlled molecular structure, the aqueous pigment dispersion can be obtained with the pigment dispersed in it. | 08-01-2013 |
20130267671 | LIVING RADICAL POLYMERIZATION METHOD - Provided is a low-cost, highly active, environmentally friendly living radical polymerization method which does not require a radical initiator. Even if a catalyst is not used, a living radical polymerization method can be conducted by controlling the amount of the oxygen in the gaseous phase in the reaction vessel within a suitable range. A monomer having a radical-reactive unsaturated bond can be subjected to a radical polymerization reaction to obtain a polymer having narrow molecular weight distribution. The cost of the living radical polymerization can be remarkably reduced. The present invention eliminates the disadvantages of the conventional catalysts such as toxicity, low solubility, coloring/odor and the like, and is significantly more environmentally friendly and economically efficient than conventional living radical polymerization methods. | 10-10-2013 |
20140303334 | CATALYST FOR LIVING RADICAL POLYMERIZATION AND POLYMERIZATION METHOD - A nonmetallic compound having an ionic bond with a halide ion is used as a catalyst for living radical polymerization. Even if a radical initiator is not used, a monomer can be subjected to a radical polymerization to obtain a polymer having narrow molecular weight distribution. The cost of the living radical polymerization can be remarkably reduced, and it is made possible to prevent adverse effects of using a radical initiator (such as side reactions). The present invention is significantly more environmentally friendly and economically excellent than conventional living radical polymerization methods, due to advantages such as low toxicity of the catalyst, low amount of the catalyst necessary, high solubility of the catalyst, mild reaction conditions, and no coloration/no odor, etc. The catalyst can be applied to various monomers and enables synthesis of high molecular weight polymers. | 10-09-2014 |
Patent application number | Description | Published |
20110136965 | PIGMENT DISPERSIONS, BLOCK POLYMERS AND MANUFACTURING METHOD THEREFOR - Disclosed is a pigment dispersion containing at least a pigment, a liquid medium and a high-molecular dispersant. The high-molecular dispersant is a block polymer represented by A-B or A-B-C, in which A, B and C each represent a polymer block and the A and C blocks may be the same or different. The block polymer and its production process are also disclosed. The high-molecular dispersant is free of problems of a smell, coloration, a heavy metal and cost, and its use can provide a pigment dispersion excellent in the dispersion stability of a pigment. | 06-09-2011 |
20110223529 | AQUEOUS PIGMENT DISPERSION AND APPLICATIONS THEREOF - Disclosed are an aqueous pigment dispersion containing at least a pigment, water, a high-molecular dispersant, and an alkali. The high-molecular dispersant is a diblock polymer having a formula (1) of A-B or a triblock polymer having a formula (2) of A-B-C. The diblock or triblock polymer is a diblock or triblock polymer obtained by polymerizing addition-polymerizable monomers with a radical generator while using an organic iodide as a polymerization initiating compound and an organic phosphorus compound, organic nitrogen compound or organic oxygen compound as a catalyst. Also disclosed are a production method and use of the aqueous pigment dispersion. With the high-molecular dispersant obtained by a simple living radical polymerization process free of the problems of conventional living radical polymerization and having a precisely-controlled molecular structure, the aqueous pigment dispersion can be obtained with the pigment dispersed in it. | 09-15-2011 |
20110275775 | CATALYST FOR LIVING RADICAL POLYMERIZATION - Provided is a catalyst used for a living radical polymerization method, which contains a central element consisting of carbon and at least one halogen atom binding to the central element. Further, a hydrocarbon compound can be used as a catalyst precursor. A monomer having a radical-reactive unsaturated bond is subjected to a radical polymerization reaction in the presence of the catalyst, consequently a polymer having narrow molecular weight distribution can be obtained, and thus the cost of the living radical polymerization can be remarkably reduced. The present invention is significantly more environmentally friendly and economically excellent than conventional living radical polymerization methods, due to advantages such as low toxicity of the catalyst, low amount of the catalyst used, high solubility of the catalyst, mild reaction conditions, and no coloration/no odor (no need of any post-treatments for a molded article), and the like. | 11-10-2011 |
20120190795 | CATALYST FOR LIVING RADICAL POLYMERIZATION AND POLYMERIZATION METHOD - Provided is a low-cost, highly active, environmentally friendly living radical polymerization catalyst which does not require a radical initiator. An organic compound having an oxidation-reduction capability is used as a catalyst. Even if a radical initiator is not used, a monomer can be subjected to a radical polymerization to obtain a polymer having narrow molecular weight distribution. The cost of the living radical polymerization can be remarkably reduced. It is made possible to prevent adverse effects of using a radical initiator. The present invention is significantly more environmentally friendly and economically excellent than conventional living radical polymerization methods, due to advantages of the catalyst such as low toxicity of the catalyst, low amount of the catalyst necessary, high solubility of the catalyst, mild reaction conditions, and no coloration/no odor (which do not require a post-treatment for a molded article), etc. | 07-26-2012 |
20120329940 | ALKOXYSILYL GROUP-CONTAINING BLOCK COPOLYMER, METHOD FOR PRODUCING THE SAME, RESIN-TREATED PIGMENT, AND PIGMENT DISPERSION - Disclosed are an alkoxysilyl-containing A-B block copolymer formed from (meth)acrylate monomers as constituent monomers, characterized in that a polymer block of A chain has a number average molecular weight (Mn) of from 1,000 to 50,000 and a molecular weight distribution (Mw/Mn) of not greater than 1.6, a polymer block of B chain comprises alkoxysilyl-containing (meth)acrylate units as constituent monomer units, and the A-B block copolymer as a whole has a molecular weight distribution of not greater than 1.6, a process for the production of the block copolymer, a resin-treated pigment, and a pigment dispersion. | 12-27-2012 |
20130012626 | RESIN-TREATED PIGMENT, METHOD FOR PRODUCING THE PIGMENT, AND PIGMENT DIPERSION - Disclosed are a resin-treated pigment characterized in that the resin-treated pigment comprises a pigment and a polymer of an unsaturated bond-containing monomer, a weight ratio of the pigment to the polymer (pigment:polymer) is from 50 to 95 to from 5 to 50, and the polymer is a block copolymer comprising from 5 to 70 mass % of an addition-polymerizable monomer having a UV-absorbing group; a production process of the resin-treated pigment; and a pigment dispersion using the resin-treated pigment. | 01-10-2013 |
20130338273 | EMULSION BINDER, AQUEOUS PIGMENT INK FOR INKJET CONTAINING SAME, AND METHOD FOR PRODUCING EMULSION BINDER - Disclosed is an emulsion binder containing an A-B block copolymer. The A-B block copolymer has a number average molecular weight of 5,000 to 100,000, and a polydispersity index (weight average molecular weight/number average molecular weight) of not greater than 1.7. The polymer block A has an acid value of 0 to 30 mgKOH/g and a glass transition point of not higher than 60° C. The polymer block B has an acid value of 75 to 250 mgKOH/g. The A-B block copolymer has been neutralized with an alkaline material, and has been allowed to self-emulsify in an aqueous medium to form emulsion particles having an average particle size of 30 to 300 nm. | 12-19-2013 |
Patent application number | Description | Published |
20130258280 | ANTERIOR OCULAR SEGMENT TOMOGRAPHIC IMAGE ANALYSIS METHOD AND ANTERIOR OCULAR SEGMENT TOMOGRAPHIC IMAGE ANALYSIS APPARATUS - To determine an opening degree of a chamber angle with higher accuracy compared to that of a conventional technology, provided is an anterior ocular segment tomographic image analysis method including: a first determination step of determining an approximated line that approximates a shape of an anterior surface of an iris along the anterior surface of the iris in an anterior ocular segment tomographic image; a second determination step of determining an approximated line extended part obtained by extending the approximated line until the approximated line crosses a baseline in contact with an inner surface of a cornea and an inner surface of a sclera of an anterior ocular segment in the anterior ocular segment tomographic image; and a calculation step of calculating an opening degree of an anterior chamber angle of the anterior ocular segment through use of the approximated line and the approximated line extended part. | 10-03-2013 |
20130258282 | OPHTHALMOLOGIC APPARATUS - An ophthalmologic apparatus includes an obtaining unit configured to obtain an anterior segment image of a subject's eye, a tomographic image obtaining unit configured to obtain a tomographic image of an anterior segment of the subject's eye, a calculation unit configured to calculate a thickness of a cornea based on the tomographic image, and a display control unit configured to cause a display unit to display the anterior segment image, a closed curve on the anterior segment image, and a smallest thickness of the cornea among thicknesses of the cornea in a portion where the closed curve lies. | 10-03-2013 |
20130258283 | OPHTHALMOLOGIC APPARATUS - An ophthalmologic apparatus includes an ophthalmologic apparatus configured to acquire unique information of a subject's eye, an acquisition unit configured to acquire a value indicating brightness of surroundings of the ophthalmologic apparatus, and a recording unit configured to record in a storing unit a value indicating brightness acquired by the acquisition unit, associated with a tomographic image. | 10-03-2013 |
20140198300 | Ophthalmic Apparatus and Ophthalmic Method - An ophthalmic apparatus includes a fundus image acquisition unit which acquires a plurality of fundus images acquired by imaging fundus of a subject's eye at different times and at least one fundus image that is fewer than the plurality of fundus images and acquired by imaging fundus of the subject's eye at a different time from those for the plurality of fundus images, a unit which generates a new fundus image by averaging the plurality of fundus images, an extraction unit which extracts a feature region from the generated new fundus image, and a unit which tracks the fundus such that positions of a first polarization tomographic image of the fundus corresponding to the new fundus image and a second polarization tomographic image of the fundus corresponding to the at least one fundus image may be corrected based on the extracted feature region and the at least one fundus image. | 07-17-2014 |